مشخصات پژوهش

صفحه نخست /Bis[(2-ethoxy-2-oxoethyl)triph
عنوان Bis[(2-ethoxy-2-oxoethyl)triphenyl phosphonium] di-µ-chloro-bis[bromochloro palladate (II)] and its application in Heck and Suzuki cross-coupling reactions
نوع پژوهش مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها Palladium(II),Heck C-C coupling,Suzuki cross-coupling,Phosphonium salt
چکیده In this study, the phosphonium salt [Ph3PCHC(O)OCH2CH3]Br undergoes a reaction with palladium(II) chloride, resulting in the formation of [Ph3PCHC(O)OCH2CH3]2[Pd2Cl4Br2]. The synthesized compound underwent thorough characterization through elemental analysis, as well as FT-IR, 1H, 31P, and 13C NMR spectroscopies. The investigation revealed that this particular substance serves as an efficient catalyst for the Heck cross-coupling reaction, leading to the synthesis of diverse unsaturated products with highly favorable outcomes. Moreover, it has demonstrated effectiveness in catalyzing the Suzuki cross-coupling reaction. Notably, the catalyst exhibits sustained catalytic activity and can be conveniently recovered and reused.
پژوهشگران ابوذر بسطامی (نفر اول)، علی نقی پور (نفر دوم)، علی خطیب جو (نفر سوم)، فرشید فتاح نیا (نفر چهارم)