عنوان	[Benzylamine-K2-C,N]1,2-Bis (Diphenylphosphino)-Propane-k2-P,P] Palladium}Perchlorate, Mononuclear Complex of Ortho-Palladated Derived from Benzylamine
نوع پژوهش	مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها	Palladium(II) complexes,C–H bond activation,Ortho-palladation,NC-Chelating,Benzylamine,Crystal structure
چکیده	This work reports the preparation of the mononuclear derivative [Pd(C6H4CH2NH2) L](ClO4) (L = dppp). The centrosymmetric mononuclear palladium complex obtained by the reaction of palladium(II) acetate with benzylamine in toluene produced the acetate cyclopalladated dimer of benzylamine. Metathesis reaction of this acetate-bridged cyclopalladated complex with NaCl in water and acetone gave N,C-orthopalladated [Pd(C6H4-CH2NH2)(l-Cl)]2 complex, which reacts with NaClO4/dppp to give the mononuclear derivative. The ortho-palladation complex was characterized by various spectroscopic techniques such as elemental analysis, IR, 1H, 31P,and 13C NMR. The structures of N,C-metalated complex 3 were determined by X-ray diffraction study.
پژوهشگران	علی نقی پور (نفر اول)، سید جواد صابونچی (نفر دوم)، محسن صیادی (نفر سوم)، محمد پناهی مهر (نفر چهارم)، بهروز نوتاش (نفر پنجم)