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عنوان
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New metal complexes supported on Fe3O4
magnetic nanoparticles as recoverable catalysts
for selective oxidation of sulfides to sulfoxides
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نوع پژوهش
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مقاله چاپشده در مجلات علمی
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کلیدواژهها
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Zr(IV) complex of Fe3O4; Cu(II) complex of Fe3O4; magnetic nanoparticles; sulfoxides
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چکیده
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Fe3O4 nanoparticles were coated with aminopropyltriethoxysilane and subsequently reacted with isatin to obtain imine-bonded Fe3O4 nanoparticles. The addition of ZrOCl28H2O or CuCl2 led to the formation of complexes of Zr(IV)/isatin@Fe3O4 or Cu (II)/ isatin@Fe3O4 as new magnetically separable catalysts. The synthesized catalysts were characterized using various techniques. These catalysts are shown to be efficient for chemo-selective oxidation of sulfides to sulfoxides using hydrogen peroxide as oxidative agent. This system has many advantages, such as excellent level of reusability ofmagnetic catalysts, high yields, simplicity of separation of catalysts using an externalmagnet, environmental benignity and ease of handling
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پژوهشگران
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مریم حجامی (نفر اول)، سمیه کلیوند (نفر دوم)
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