عنوان
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Copper(II) immobilized on Fe3O4@SiO2@L-Histidine: a reusable
nanocatalyst and its application in the synthesis of 5-substituted
1H-tetrazoles
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نوع پژوهش
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مقاله چاپشده در مجلات علمی
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کلیدواژهها
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SOLVENT-FREE CONDITIONS; MAGNETIC NANOPARTICLE; CATALYZED SYNTHESIS; RECYCLABLE CATALYST; SELECTIVE OXIDATION; EFFICIENT SYNTHESIS; HYDROGEN-PEROXIDE; HIGHLY EFFICIENT; SULFURIC-ACID; IONIC LIQUID
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چکیده
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Herein, we report the synthesis and application of Cu(II) immobilized on Fe3O4@SiO2@L-Histidine, which was characterized by FTIR spectroscopy, X-ray diffraction, thermogravimetric analysis, scanning electron microscopy and atomic absorption spectroscopy. The obtained nanoparticles were employed as a heterogeneous catalyst for the synthesis of 5-substituted 1H-tetrazoles via [3?2] cycloaddition reactions of various organic nitriles with sodium azide in polyethylene glycol as solvent. The catalyst did not undergo metal leaching and could be easily recovered and reused many times.
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پژوهشگران
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گوهر آزادی (نفر اول)، آرش قربانی چقامارانی (نفر دوم)، لطفی شیری (نفر سوم)
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