عنوان	Synthesis, crystal structure study and high efficient catalytic activity of di-mu bromo-trans-dibromobls[(benzyl)(4-methylphenyl)(phenyl) phosphine] dipalladium(II) in Suzuki-Miyaura and Heck-Mizoroki C-C coupling reactions
نوع پژوهش	مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها	Phosphonium salt Palladium(II) chloride Suzuki reaction Heck reaction C-C coupling reaction
چکیده	The current research aims to present a straightforward synthesis of binuclear palladated triphenylphosphine derivative by the reaction of the phosphonium salt [(PhCH2)P(Ph)2(Ph-4-CH3)]Br with palladium(II) chloride and to afford the dimeric palladated complex {Pd[P(Ph)(CH2Ph)(Ph-4-CH3)]((l-Br)Br)}2. Moreover, elemental analysis (CHN), FT-IR, 1H, 31P, 13C NMR and X-ray crystallography led to the characterization of the obtained compound. Finally, This compound was found to be an efficient catalyst in C–C bond formation between various aryl halides with phenylboronic acid (Suzuki–Miyaura reaction) and aryl halides with n-butyl acrylate (Heck–Mizoroki reaction).
پژوهشگران	آرش قربانی چقامارانی (نفر اول)، علی نقی پور (نفر دوم)، حشمت اله بابایی (نفر سوم)، بهروز نوتاش (نفر چهارم)