عنوان
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Cu(II)–Schiff base complex-functionalized
magnetic Fe3O4 nanoparticles: a heterogeneous
catalyst for various oxidation reactions
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نوع پژوهش
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مقاله چاپشده در مجلات علمی
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کلیدواژهها
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magnetic Fe3O4; nanoparticles; hydrogen peroxide; oxidation; thiol; sulfide
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چکیده
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Cu(II)–Schiff base complex-functionalized magnetic Fe3O4 nanoparticles were prepared and characterized using Fourier transform infrared spectroscopy, thermogravimetric analysis and scanning electron microscopy techniques. This compound acts as a highly active and selective catalyst for the oxidation of sulfides and thiols. These reactions can be carried out in ethanol or solvent-free conditions in the presence of hydrogen peroxide with complete selectivity and very high conversion under mild reaction conditions. The designed catalytic system prevents effectively the over-oxidation of sulfides to sulfones. Separation and recycling can also be easily done using a simple magnetic separation process
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پژوهشگران
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آرش قربانی چقامارانی (نفر اول)، زهرا درویش نژاد (نفر دوم)، معصومه نوروزی (نفر سوم)
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