عنوان
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Study of Crystallinity of High-density Polyethylene by Inverse Gas Chromatography
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نوع پژوهش
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مقاله چاپشده در مجلات علمی
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کلیدواژهها
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high-density polyethylene (HDPE), crystallinity, inverse gas chromatography, retention diagram, soaking method
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چکیده
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Method of inverse gas chromatography (IGC) has been used for the physicochemical characterization of polymers for more than two decades . In this method the polymeric stationary phase could be characterized by using probe molecules . The retention volume of probe is a measure of the polymer-probe interaction and show changes in the polymer structure at melting point or glass transition temperature . Crystallinity of high-density polyethylenes (HOPE) of Poliran and Irapol from Iranian petrochemical companies was studied . The effects of the flow rates and the sample size on peak retention volume were investigated . Modified techniques for measurement of flow rate and coating were used . Retention diagram and degree of crystallinity were determined for a sample of low-density polyethylene and the results were compared with those obtained for HDPE . Experimental data of crystallinity and melting points showed that the Iranian HDPE is a polymer with suitable engineering properties
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پژوهشگران
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موسی قائمی (نفر اول)، محمد رضا حاج محمدی (نفر دوم)، رضا تبارکی (نفر سوم)
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