عنوان
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Electrochemical Detection of Persulfate at the Modified
Glassy Carbon Electrode with Nanocomposite Containing
Nano-Ruthenium Oxide/Thionine and Nano-Ruthenium
Oxide/Celestine Blue
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نوع پژوهش
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مقاله چاپشده در مجلات علمی
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کلیدواژهها
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Persulfate · Ruthenium oxide nanoparticles · Thionine · Celestin blue · Electrocatalytic
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چکیده
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The present study describes the fabrication of a sensitive amperometric sensor for the determination of persulfate. The immobilization surface was prepared by modifying a glassy carbon (GC) electrode with a nanocomposite containing ruthenium oxide (RuOx) nanoparticles and thionine (TH) or celestin blue (CB). The modified electrodes indicated excellent electrocatalytic activity toward persulfate reduction at a potential of +0.1 V. The proposed sensor showed detection limits of 1.46 mM for the GC/RuOx/TH modified electrode and 2.64 mM for the GC/RuOx/CB modified electrode. The sensitivities were obtained as 3 nAmM1 at a concentration range of 10 mM to 11 mM for the GC/RuOx/TH modified electrode and 1 nAmM1 at a concentration range of 10 mM to 6 mM for the GC/RuOx/CB modified electrodes
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پژوهشگران
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محمود روشنی (نفر اول)، الهام کرمی (نفر دوم)
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