عنوان	The effect of encapsulated Zn-POM on the catalytic activity of MIL-101 in the oxidation of alkenes with hydrogen peroxide
نوع پژوهش	مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها	Metal–organic framework,MIL-101,Supported polyoxometalate,Alkene oxidation,Hydrogen peroxide,Nanoporous material
چکیده	Zinc monosubstituted Keggin heteropolyanion [PZnMo2W9O39]5 was electrostatically bound to nanocages of MIL-101 polymer matrix. The Zn-POM@MIL-101 catalyst was characterized by XRD, N2 adsorption, atomic absorption (AAS), and FT-IR spectroscopic methods. The catalytic activity of the new composite material, Zn-POM@MIL-101, was assessed in the oxidation of alkenes using aqueous hydrogen peroxide as oxidant. Zn-POM@MIL-101/H2O2 catalytic system demonstrated good catalytic activity in the oxidation reactions. Zn-POM@MIL-101 was reusable for three catalytic cycles. While the MIL-101 matrix is an active catalyst in these oxidatio
پژوهشگران	زهرا ساعدی (نفر اول)، شهرام تنگستانی نژاد (نفر دوم)، مجید مقدم (نفر سوم)، ولی اله میرخانی (نفر چهارم)، ایرج محمدپور بلترک (نفر پنجم)