عنوان	Dative and covalent-dative postsynthetic modification of a two-fold interpenetration pillared-layer MOF for heterogeneous catalysis: A comparison of catalytic activities and reusability
نوع پژوهش	مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها	Metal-organic frameworks,Postsynthetic modification,Heterogeneous catalysis,Molybdenum(VI),Oxidation
چکیده	Two MOF-supported Mo(VI) oxidation catalysts bearing N,O-chelating ligand were synthesized via dative and covalent-dative postsynthetic modifications of a two-fold interpenetration pillared-layer aminefunctionalized MOF known as TMU-16-NH2. These post-functionalized catalysts were characterized by FT-IR spectroscopy, thermogravimetric analysis, ICP and X-ray powder diffraction techniques. The Mo(VI)-containing MOFs exhibit both epoxide selectivity and fully reusability for alkenes epoxidation by tert-butylhydroperoxide (TBHP).
پژوهشگران	زهرا ساعدی (نفر اول)، وحید صفری فرد (نفر دوم)، علی مرسلی (نفر سوم)