عنوان	Irreversible replacement of sodium with thallium in sodium coordination polymer nanostructures by solid‑state mechanochemical cation exchange process
نوع پژوهش	مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها	Coordination polymer,Sonochemical,Mechanochemical,Solid state,Sodium,Nanostructure
چکیده	Solid-state conversion of NaI coordination polymer nanostructure, synthesized by sonochemical procedure, to TlI coordination polymer has been observed upon liquid-assisted mechanochemical reaction of [ Na2TP]n (1) ( H2TP = terephthalic acid), with TlNO3. During this conversion, ion exchange process of Na(I) with Tl(I) was occurred and [ Tl2TP]n (2) was synthesized. The X-ray diffraction (XRD) pattern of 2 after mechanochemical reaction of it with NaNO3 indicated that this transformation is irreversible. Compounds 1 and 2 were characterized by IR spectroscopy, X-ray powder diffraction (XRD), elemental analysis, thermogravimetric and differential thermal analyses and scanning electron microscopy.
پژوهشگران	کامران اخباری (نفر اول)، سپیده کرمی (نفر دوم)، آنکورن فورانگرت (نفر سوم)، زهرا ساعدی (نفر چهارم)