عنوان
|
Chemoselective Oxidation of Sulfides with Ammonium Nitrate and Silica Sulfuric Acid Catalyzed by KBr
|
نوع پژوهش
|
مقاله چاپشده در مجلات علمی
|
کلیدواژهها
|
sulfide; sulfoxide; chemoselectivity; ammonium nitrate; potassium bromide; silica sulfuric acid
|
چکیده
|
Abstract A convenient and selective catalytic method for the sulfoxidation of aliphatic and aromatic sulfides by treatment of NH4NO3, silica sulfuric acid, wet SiO2 (50% w/w) and a catalytic amount of KBr in CH2Cl2 at room temperature was developed. Many sulfides can be selectively oxidized at room temperature in good to excellent yields. The reaction proceeds without over-oxidation to sulfones under mild conditions.
|
پژوهشگران
|
آرش قربانی چقامارانی (نفر اول)، محمد علی زلفی گل (نفر دوم)، تکتم رستگار (نفر سوم)
|