عنوان
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1,3-Dichloro-5,5-Dimethylhydantoin (DCH) and Trichloromelamine (TCM) as Efficient Catalysts for the Chemoselective Trimethylsilylation of Hydroxyl Group with 1,1,1,3,3,3-Hexamethyldisilazane (HMDS) Under Mild Conditions
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نوع پژوهش
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مقاله چاپشده در مجلات علمی
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کلیدواژهها
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1,3-Dichloro-5,5-dimethylhydantoin (DCH); Trichloromelamine (TCM); Trimethylsilylation; Hexamethyldisilazane (HMDS)
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چکیده
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A highly convenient method for the trimethylsilylation of alcohols and phenols via treatment by hexamethyldisilazane in the presence of 1,3-dichloro-5,5-dimethylhydantoin (DCH) and/or trichloromelamine (TCM) as a catalyst has been developed. A wide variety of hydroxyl groups were selectively protected in CH(2)Cl(2)/CH(3)CN under mild conditions.
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پژوهشگران
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آرش قربانی چقامارانی (نفر اول)، کمال امانی (نفر دوم)، محمد علی زلفی گل (نفر سوم)، مریم حجامی (نفر چهارم)، رویا ایازی نصرآبادی (نفر پنجم)
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