عنوان	Metal-free catalytic oxidation of sulfides to sulfoxides with ammonium nitrate, ammonium hydrogen sulfate and ammonium bromide as catalyst
نوع پژوهش	مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها	sulfides; sulfoxide; ammonium hydrogen sulfate (NH(4)HSO(4)); ammonium nitrate (NH(4)NO(3)); ammonium bromide (NH(4)Br); homoselectivity
چکیده	A general and metal-free catalytic oxidation of aliphatic and aromatic sulfides to their corresponding sulfoxides via combination of ammonium nitrate (NH(4)NO(3)), supported ammonium hydrogen sulfate on silica gel (NH(4)HSO(4)-SiO(2)) and a catalytic amount of ammonium bromide (NH(4)Br) in the presence of wet SiO(2) (50%, w/w) has been investigated. The reactions were carried out heterogeneously and selectively in short reaction times in CH(2)Cl(2) at room temperature. This protocol is mild and efficient compared to other reported methods.
پژوهشگران	آرش قربانی چقامارانی (نفر اول)، محمد علی زلفی گل (نفر دوم)، رویا ایازی نصرابادی (نفر سوم)