عنوان
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Polyvinylpolypyrrolidoniume tribromide as new and metal-free catalyst for the formylation and trimethylsilylation of hydroxyl group
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نوع پژوهش
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مقاله چاپشده در مجلات علمی
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کلیدواژهها
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Polyvinylpolypyrrolidone; Polyvinylpolypyrrolidoniume tribromide; Formylation; Silylation; Ethyl format; 1,1,3,3-Hexamethyldisilazane (HMDS)
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چکیده
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Abstract Trimethylsilylation of alcohols was achieved using 1,1,1,3,3,3-hexamethyldisilazane (HMDS) as silylating agent, in the presence of polyvinylpolypyrrolidoniume tribromide in acetonitrile at room temperature. Also a variety of alcohols were converted into alkyl formates by ethyl formate and a catalytic amount of polyvinylpolypyrrolidoniume tribromide under solvent free conditions at room temperature.
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پژوهشگران
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آرش قربانی چقامارانی (نفر اول)، حمید گودرزی افشار (نفر دوم)، پریسا زمانی (نفر سوم)
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