عنوان	Ordered mesoporous SBA-15 functionalized with yttrium(III) and cerium(III) complexes: Towards active heterogeneous catalysts for oxidation of sulfides and preparation of 5-substituted 1H -tetrazoles
نوع پژوهش	مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها	heterogeneous catalyst; SBA-15; sulfoxides; tetrazoles; yttrium and cerium
چکیده	Mesoporous SBA-15 was synthesized and modified with 3-chloropropyltrimethoxysilane and then used in immobilization of creatinine groups, which were employed to introduce Y3+ and Ce3+ to give rise to two novel yttrium and cerium catalysts: SBA-15@Creatinine@M (M = Y and Ce). The structures of the SBA-15@Creatinine@M catalysts were determined using various techniques. These catalysts offered outstanding catalytic performances in the oxidation of sulfides to sulfoxides and in the preparation of 5-substituted 1H-tetrazoles. An important characteristic of the SBA-15@Creatinine@M catalysts is that they are very stable without a considerable decrease in their catalytic performance lasting seven cycles.
پژوهشگران	سمیه مولایی (نفر اول)، طیبه طامرادی (نفر دوم)، محمد قادرمزی (نفر سوم)، آرش قربانی چقامارانی (نفر چهارم)