مشخصات پژوهش

صفحه نخست /A copper complex stabilized ...
عنوان A copper complex stabilized on boehmite nanoparticles as an efficient nanocatalyst for the selective synthesis of diaryl ethers
نوع پژوهش مقاله ارائه شده کنفرانسی
کلیدواژه‌ها Boehmite nanoparticles,ether derivatives,coupling reaction,C-O coupling reactions,copper complex
چکیده In this work boehmite nanoparticles (NPs) were synthesized from NaOH and Al(NO3)3.9H2O solutions. Then, the surface of boehmite NPs was modified by (3-chloropropyl)trimethoxysilane and further Schiff-base ligand (MP-bis(AMP)) was immobilized on its surface. At final step, a copper complex was stabilized on the surface of modified boehmite NPs (Cu(II)-MP-bis(AMP)@boehmite). These obtained nanoparticles were characterized using SEM, EDS, WDX, AAS, TGA, BET, FT-IR, and XRD techniques. In continue, the catalytic activity of Cu(II)-MP-bis(AMP)@boehmite has been investigated in the synthesis of biphenyl ether derivatives through C-O coupling reaction. C-O coupling reaction is a powerful tool for the synthesis of ether derivatives [1-4]. Cu(II)-MP-bis(AMP)@boehmite catalyst has been reused for several times in the synthesis of ether derivatives.
پژوهشگران آریدا جباری (نفر اول)، پریسا مرادی (نفر دوم)، مریم حجامی (نفر سوم)، بهمن طهماسبی (نفر چهارم)