مشخصات پژوهش

صفحه نخست /Development of an ...
عنوان Development of an electrochemical sensor using electropolymerization of α-Cyclodextrin for the selective detection of copper (II) ions
نوع پژوهش مقاله چاپ‌شده در مجلات علمی
کلیدواژه‌ها Copper (II) ion Electrochemical sensor DPASV Copper is an essential nutrient for all living organisms, and its deficiency or high levels can have detrimental effects on health. On the other hand, as a heavy metal, it is a highly toxic environmental pollutant. Consequently, it is essential to develop a selective and simple sensor for Cu 2+ detection. Here, the electrochemical sensor was designed through the glassy carbon electrode (GCE) modification based on electropolymerization of Electropolymerization α-Cyclodextrin
چکیده Copper is an essential nutrient for all living organisms, and its deficiency or high levels can have detrimental effects on health. On the other hand, as a heavy metal, it is a highly toxic environmental pollutant. Consequently, it is essential to develop a selective and simple sensor for Cu2+ detection. Here, the electrochemical sensor was designed through the glassy carbon electrode (GCE) modification based on electropolymerization of α-Cyclodextrin (Pα-CD) to detect copper (II) ions. The modified GCE was characterized through field emission scanning electron microscopy (FE-SEM), electrochemical impedance spectroscopy (EIS), cyclic voltammetry (CV), and differential pulse anodic stripping voltammetry (DPASV), by these methods was exhibited that the conductive polymer (Pα-CD) is coating the GCE surface. The two linear ranges were provided for Cu2+ from 0.004 to 5 nM and 5 to 1100 nM with detection limit (LOD) of 0.0013 nM. The introduced electrode displayed the capability for the selective detection of Cu2+ in the presence of different ions. Moreover, the sensor was successfully employed to detect Cu2+ in soil and water samples. The validation was carried out through cold vapor atomic absorption spectrometry (CVAAS) to detect the Cu2+ in the real samples.
پژوهشگران محمود روشنی (نفر اول)، زهرا میرزایی کارزانی (نفر دوم)، حسن سعید حمداله (نفر سوم)