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Arash Ghorbani-Choghamarani

Academic rank: Professor
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Education: PhD.
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Faculty: Basic Science
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Research

Title
Synthesis and characterization of Copper (II) Schiff base complex containing MCM-41 as robust and clean nano reactor catalyst for the selective oxidation of sulfides to sulfoxides using H2O2
Type
JournalPaper
Keywords
Mesoporous silica MCM-41 Cu (II) Schiff base complex Heterogeneous Sulfoxides Hydrogen peroxide Salen
Year
2016
Journal JOURNAL OF POROUS MATERIALS
DOI
Researchers Houri Mahdavi ، Mohsen Nikoorazm ، Arash Ghorbani-Choghamarani ، Sattar Arshadi

Abstract

An efficient and versatile procedure has been introduced for the preparation of copper supported on functionalized mesoporous silica (MCM-41) containing chelating Schiff base salen (the structure of this functionalized silica complex was studied by X-ray diffraction, transmission electron microscopy, Fourier transform infrared spectroscopy, thermo gravimetric analysis and N2 adsorption and desorption), which has been applied as catalyst for the conversion of various sulfides into sulfoxides with aqueous hydrogen peroxide. Also this heterogeneous catalyst can be recovered easily and reused many times for the oxidation of sulfides without significant loss of activity and selectivity