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Arash Ghorbani-Choghamarani

Academic rank: Professor
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Education: PhD.
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Faculty: Basic Science
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Research

Title
Pd(0)-Arg-boehmite: As Reusable and Efcient Nanocatalyst in Suzuki and Heck Reactions
Type
JournalPaper
Keywords
Boehmite nanoparticles; Arginine; Palladium; Suzuki reaction; Heck reaction; C-C coupling
Year
2017
Journal catalysis letters
DOI
Researchers Bahman Tahmasbi ، Arash Ghorbani-Choghamarani

Abstract

The direct supporting of Pd-arginine complex on boehmite nanoparticles (Pd(0)-Arg-boehmite) was reported as a moisture- and air-stable, heterogeneous, excellent and novel organometallic catalyst, which applied for the Suzuki and Heck cross coupling reactions through coupling of phenylboronic acid, 3,4-difluoro phenylboronic acid, sodium tetraphenyl borate, butyl acrylate, methyl acrylate, acrylonitrile and styrene with a wide range of aryl halide including Cl, Br and I. Pd(0)-Arg-boehmite was prepared for the frst time via simple, environmental and inexpensive procedure in water and ethanol without inert atmosphere or high temperature using commercially available materials, and characterized by XRD, TGA, TEM,SEM, EDS and ICP-OES techniques. The leaching of palladium and heterogeneity test of this catalyst was studied by hot fltration and ICP-OES techniques; resulting we found that this catalyst was demonstrated remarkable and excellent recyclability