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Arash Ghorbani-Choghamarani

Academic rank: Professor
ORCID:
Education: PhD.
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Faculty: Basic Science
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Research

Title
PdeS-methylisothiourea supported on magnetic nanoparticles as an efficient and reusable nanocatalyst for Heck and Suzuki reactions
Type
JournalPaper
Keywords
Magnetic nanoparticle Heck reaction Suzuki reaction CeC coupling Palladium
Year
2017
Journal COMPTES RENDUS CHIMIE
DOI
Researchers Arash Ghorbani-Choghamarani ، Bahman Tahmasbi ، Nourolah Noori ، Sara Faryadi

Abstract

Supported PdeS-methylisothiourea on magnetic nanoparticles (PdeSMU-MNPs) as an efficient and magnetically reusable nanocatalyst was prepared and applied for the Heck and Suzuki cross-coupling reactions. All coupling reactions proceeded in short reaction times with good to excellent yields. After completion of reactions, the catalyst was easily separated from the reaction mixture using an external magnetic field and reused for several consecutive runs without significant loss of its catalytic efficiency and activity. This nanomagnetic catalyst was characterized by FT-IR spectroscopy, XRD, VSM, ICP-OES, TEM and SEM techniques. The leaching of the catalyst has been examined by a hot filtration test and ICP-OES analysis.