2025/12/21

Arash Ghorbani-Choghamarani

Academic rank: Professor
ORCID:
Education: PhD.
H-Index:
Faculty: Basic Science
ScholarId:
E-mail: a.ghorbani [at] ilam.ac.ir
ScopusId:
Phone:
ResearchGate:

Research

Title
Suzuki, Stille and Heck cross-coupling reactions catalyzed by Fe3O4@PTA–Pd as a recyclable and efficient nanocatalyst in green solvents
Type
JournalPaper
Keywords
MAGNETIC NANOPARTICLES; HETEROGENEOUS ORGANOCATALYST; HIGHLY EFFICIENT; WATER; OXIDATION; LIGANDS; POLYMER; HALIDES
Year
2016
Journal NEW JOURNAL OF CHEMISTRY
DOI
Researchers Arash Ghorbani-Choghamarani ، Masoomeh Norouzi

Abstract

The use of a supported Pd complex on magnetic nanoparticles as an efficient and green catalyst for the Suzuki, Stille and Heck cross-coupling reactions is presented. The present research is focused on investigating the recycling, reusability and stability of the catalyst in the reaction. The recycled Fe3O4@PTA–Pd catalyst was used at least five times with comparable activities to that of the fresh catalyst. The catalytic coupling of 4-bromotoluene as a model reaction suggested that there was no leached palladium in the reaction mixture. The structure of the catalyst was characterized by TGA, EDS, ICP-OES, XRD, VSM, FT-IR and SEM analysis