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Arash Ghorbani-Choghamarani

Academic rank: Professor
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Education: PhD.
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Faculty: Basic Science
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Research

Title
Cu(II)–Schiff base complex-functionalized magnetic Fe3O4 nanoparticles: a heterogeneous catalyst for various oxidation reactions
Type
JournalPaper
Keywords
magnetic Fe3O4; nanoparticles; hydrogen peroxide; oxidation; thiol; sulfide
Year
2015
Journal APPLIED ORGANOMETALLIC CHEMISTRY
DOI
Researchers Arash Ghorbani-Choghamarani ، Zahra Darvishnejad ، Masoomeh Norouzi

Abstract

Cu(II)–Schiff base complex-functionalized magnetic Fe3O4 nanoparticles were prepared and characterized using Fourier transform infrared spectroscopy, thermogravimetric analysis and scanning electron microscopy techniques. This compound acts as a highly active and selective catalyst for the oxidation of sulfides and thiols. These reactions can be carried out in ethanol or solvent-free conditions in the presence of hydrogen peroxide with complete selectivity and very high conversion under mild reaction conditions. The designed catalytic system prevents effectively the over-oxidation of sulfides to sulfones. Separation and recycling can also be easily done using a simple magnetic separation process