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Arash Ghorbani-Choghamarani

Academic rank: Professor
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Education: PhD.
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Faculty: Basic Science
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Research

Title
Anchoring of Pd(II) complex in functionalized MCM- 41 as an efficient and recoverable novel nano catalyst in C–C, C–O and C–N coupling reactions using Ph3SnCl
Type
JournalPaper
Keywords
MESOPOROUS MOLECULAR-SIEVES; SILICA NANOPARTICLES; HECK REACTIONS; SUZUKI; CARBON
Year
2015
Journal RSC ADVANCES
DOI
Researchers Arash Ghorbani-Choghamarani ، Farzad Nikpour ، Farshid Ghorbani ، Forugh Havasi

Abstract

Anchored palladium(II) in functionalized MCM-41 mesoporous silica was prepared and used as an efficient, recoverable and thermally stable heterogeneous nano catalyst for C–C, C–O and C–N bond formation in cross-coupling reactions in the presence of Ph3SnCl. MCM-41 was prepared trough hydrothermal synthesis using tetraethyl orthosilicate (Si(OC2H5)4) as silica source and cetyltrimethylammonium bromide (CTAB) as a template. The structure of functionalized MCM-41 was studied by FT-IR, XRD, SEM, TEM, TGA, EDS, ICP and BET techniques.