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Arash Ghorbani-Choghamarani

Academic rank: Professor
ORCID:
Education: PhD.
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Faculty: Basic Science
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Research

Title
SELECTIVE OXIDATION OF SULFIDES TO SULFOXIDES USING H2O2 CATALYZED BY p-TOLUENESULFONIC ACID (p-TsOH) UNDER SOLVENT-FREE CONDITIONS
Type
JournalPaper
Keywords
p-TsOH; catalyst; hydrogen peroxide; sulfide; oxidation; sulfoxide
Year
2013
Journal Phosphorus, Sulfur and Silicon and the Related Elements
DOI
Researchers Amin Rostami ، Fatemeh Hassanian ، Arash Ghorbani-Choghamarani ، Shaghayegh Saadati

Abstract

An efficient, chemoselective, and environmental friendly procedure for the oxidation of sulfides to sulfoxides is described. Various types of aromatic and aliphatic sulfides are selectively oxidized to sulfoxides in good to excellent yields using 30% H2O2 in the presence of catalytic amounts of a p-TsOH under solvent-free conditions at room temperature.