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Arash Ghorbani-Choghamarani

Academic rank: Professor
ORCID:
Education: PhD.
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Faculty: Basic Science
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Research

Title
SULFAMIC ACID-CATALYZED OXIDATION OF SULFIDES TO SULFOXIDES AND SULFONES USING H2O2: GREEN AND CHEMOSELECTIVE METHOD
Type
JournalPaper
Keywords
Catalyst; hydrogen peroxide; oxidation; sulfamic acid; sulfide; sulfone; sulfoxide
Year
2012
Journal SYNTHETIC COMMUNICATIONS
DOI
Researchers Hadi Jafari ، Amin Rostami ، Firoz Ahmad-Jangi ، Arash Ghorbani-Choghamarani

Abstract

A mild, efficient, green, and selective oxidation method of sulfides to sulfoxides or sulfones using H2O2 in the presence of catalytic amounts of sulfamic acid has been developed. Various substituted sulfides having functional groups such as alcohol, ester, and aldehyde are successfully and selectively oxidized without affecting the sensitive functionalities in good to excellent yields at room temperature.