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Arash Ghorbani-Choghamarani

Academic rank: Professor
ORCID:
Education: PhD.
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Faculty: Basic Science
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Research

Title
An Efficient Catalytic Procedure for the Selective Oxidation of Sulfides to Sulfoxides by Citric Acid/Al(NO3)3.9H2O/MBr Under Mild and Heterogeneous Conditions
Type
JournalPaper
Keywords
Sulfides; Sulfoxides; Aluminum nitrate (Al(NO3)(3)center dot 9H(2)O); Citric acid; Catalyst
Year
2009
Journal JOURNAL OF THE CHINESE CHEMICAL SOCIETY
DOI
Researchers Arash Ghorbani-Choghamarani ، Somaieh Rezaei

Abstract

A wide range of aliphatic or aromatic sulfides are selectively oxidized to the corresponding sulfoxides using Al(NO3)(3)center dot 9H(2)O, citric acid and a catalytic amount of KBr or NaBr in the presence of wet SiO2 (50% w/w) in CH2Cl2 under mild and heterogeneous conditions in good to high yields.