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Arash Ghorbani-Choghamarani

Academic rank: Professor
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Education: PhD.
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Faculty: Basic Science
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Research

Title
Aromatization of Hantzsch 1,4-Dihydropyridines with Al(NO3)3·9H2O and/or Fe(NO3)3·9H2O in the Presence of Silica Sulfuric Acid Under Mild and Heterogeneous Conditions
Type
JournalPaper
Keywords
Aluminum nitrate [Al(NO3)3 center dot 9H2O]; aromatization; 1; 4-dihydropyridines; ferric nitrate [Fe(NO3)3 center dot 9H2O]; silica sulfuric acid [SiO2-OSO3H]
Year
2010
Journal SYNTHETIC COMMUNICATIONS
DOI
Researchers Arash Ghorbani-Choghamarani ، Javad Zeinivand

Abstract

A simple and convenient method for the aromatization of Hantzsch 1,4-dihydropyridines to the corresponding pyridines is achieved via combination of aluminum or ferric nitrates and silica sulfuric acid as environmentally friendly and novel oxidizing media. This oxidation was carried out in dichloromethane under heterogeneous conditions with good to excellent yields.