Abstract Chiral cobalt metal–organic framework based on peptide with aspartic acid as building block has been synthesized and characterized by FTIR, TGA, DSC, SEM, TEM, BET and X-ray diffraction analysis. The catalytic activity of Co-P-MOFs was applide for asymmetric sulfoxidative cross-coupling using poly sulfinylpiperazine as a novel sulfoxide transfer reagent. The Co-P-MOF canberecycled several times without lossinactivity.
