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Arash Ghorbani-Choghamarani

Academic rank: Professor
ORCID:
Education: PhD.
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Faculty: Basic Science
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Research

Title
A new Pd-Schiff-base complex on boehmite nanoparticles: Its application in Suzuki reaction and synthesis of tetrazoles
Type
JournalPaper
Keywords
boehmite nanoparticles,organometallic catalyst,palladium,schiff‐base,tetrazoles
Year
2018
Journal APPLIED ORGANOMETALLIC CHEMISTRY
DOI
Researchers Arida Jabbari ، Bahman Tahmasbi ، Mohsen Nikoorazm ، Arash Ghorbani-Choghamarani

Abstract

Boehmite nanoparticles are not air or moisture sensitive, therefore have been prepared in water without inert atmosphere using inexpensive materials. Pd-isatin-boehmite was synthesized and used as heterogeneous organometallic catalyst for the synthesis of 5-substituted 1H-tetrazoles and C-C band formation. Pd-isatin-boehmite characterized by XRD, TGA, SEM and ICP-OES techniques. This catalyst was reused for several times without significant loss of its catalytic efficiency or palladium leaching. Heterogeneity of this catalyst has been studied using ICP-OES technique.