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Ali Naghipour

Academic rank: Associate Professor
ORCID:
Education: PhD.
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HIndex:
Faculty: Basic Science
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Research

Title
Heterogeneous Fe3O4@chitosan-Schiff base Pd nanocatalyst: Fabrication, characterization and application as highly efficient and magnetically-recoverable catalyst for Suzuki-Miyaura and Heck-Mizoroki C-C coupling reactions
Type
JournalPaper
Keywords
Magnetically-recoverable nanocatalyst,Fe3O4 nanoparticles,Chitosan-Schiff base complex,Suzuki–Miyaura coupling,Mizoroki–Heck coupling
Year
2015
Journal CATALYSIS COMMUNICATIONS
DOI
Researchers Ali Naghipour ، Akram Fakhri

Abstract

An environmentally friendly palladium-based catalyst supported on magnetite nanoparticles was successfully prepared. FT-IR, XRD, VSM, SEM, EDS and TGA studies have been used to characterize the nanocatalyst. The catalytic activity of the as-prepared catalyst was evaluated as a heterogeneous catalyst for the Suzuki-Miyaura carbon-carbon cross-coupling reaction of aryl halides and phenylboronic acid. Furthermore, it was found that the catalyst showed a high activity for the Mizoroki-Heck reaction of aryl halides and n-butyl acrylate. Interestingly, the novel catalyst could be recovered in a facile manner from the reaction mixture and recycled consecutive five runs without any significant loss in activity.