Na-ZSM-5 zeolite, synthesized by extended Charnell’s method was used to prepare Pt/ZSM-5 catalyst for n-pentane hydroisomerization. The influence of ion exchange, alkaline treatment and method of platinum incorporation on the Na-ZSM-5 zeolite was investigated. It was found that the presence of Trien affected the physicochemical properties of the synthesized catalyst. The synthesized catalysts showed high performance so that the sample prepared in rotating mode at 24 h and Pt loaded via impregnation showed conversion and selectivity about 75 and 97%, respectively. Also, a maximum yield for this catalyst was achieved at 250 C