2025 : 9 : 29
Bahman Tahmasbi

Bahman Tahmasbi

Academic rank: Assistant Professor
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Education: PhD.
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Faculty: Basic Science
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Research

Title
A copper complex stabilized on boehmite nanoparticles as an efficient nanocatalyst for the selective synthesis of diaryl ethers
Type
Presentation
Keywords
Boehmite nanoparticles,ether derivatives,coupling reaction,C-O coupling reactions,copper complex
Year
2022
Researchers Arida Jabbari ، Parisa Moradi ، Maryam Hajjami ، Bahman Tahmasbi

Abstract

In this work boehmite nanoparticles (NPs) were synthesized from NaOH and Al(NO3)3.9H2O solutions. Then, the surface of boehmite NPs was modified by (3-chloropropyl)trimethoxysilane and further Schiff-base ligand (MP-bis(AMP)) was immobilized on its surface. At final step, a copper complex was stabilized on the surface of modified boehmite NPs (Cu(II)-MP-bis(AMP)@boehmite). These obtained nanoparticles were characterized using SEM, EDS, WDX, AAS, TGA, BET, FT-IR, and XRD techniques. In continue, the catalytic activity of Cu(II)-MP-bis(AMP)@boehmite has been investigated in the synthesis of biphenyl ether derivatives through C-O coupling reaction. C-O coupling reaction is a powerful tool for the synthesis of ether derivatives [1-4]. Cu(II)-MP-bis(AMP)@boehmite catalyst has been reused for several times in the synthesis of ether derivatives.