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lotfi shiri

Academic rank: Assistant Professor
ORCID:
Education: PhD.
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HIndex:
Faculty: Basic Science
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Research

Title
Chemoselective Oxidation of Benzylic Alcohols and Hydroquinones with bis-(2,4,6-Trimethylpyridinium) Dichromate (BTMPDC) as an Efficient and New Oxidizing Agent
Type
JournalPaper
Keywords
Alcohols; bis-(2; 4; 6-trimethylpyridinium) dichromate; hydroquinone; oxidation
Year
2009
Journal Phosphorus, Sulfur and Silicon and the Related Elements
DOI
Researchers lotfi shiri ، Arash Ghorbani-Choghamarani

Abstract

A simple, efficient, and chemoselective oxidation of benzylic alcohols to the corresponding aldehydes and ketones and also hydroquinones to the benzoquinones using bis-(2,4,6-trimethylpyridinium) dichromate (BTMPDC) in acetonitrile is described. A good range of primary and secondary benzylic alcohols and a limited range of hydroquinones were selectively oxidized under reflux conditions in reasonable yields.