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lotfi shiri

Academic rank: Assistant Professor
ORCID:
Education: PhD.
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Faculty: Basic Science
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Research

Title
Tribromide ion immobilized on magnetic nanoparticles as an efficient catalyst for the rapid and chemoselective oxidation of sulfides to sulfoxides
Type
JournalPaper
Keywords
Magnetic nanoparticles; oxidation; sulfoxides; sulfides; tribromide
Year
2016
Journal Phosphorus, Sulfur and Silicon and the Related Elements
DOI
Researchers lotfi shiri ، Bahman Tahmasbi

Abstract

Tris(tetraalkyl ammonium tribromide) immobilized on Fe3O4 magnetic nanoparticles (Br3-Fe3O4) is a stable, green, and magnetically recoverable source of bromine and used as an efcient nanocatalyst for the clean and rapid oxidation of sulfdes to sulfoxides using hydrogen peroxide (H2O2), with short reaction times in good to high yields under solvent-free conditions. After completing reactions, the catalyst was easily separated using an external magnetic feld from the reaction mixture and reused for several consecutive runs without signifcant loss of its catalytic efciency. The nanomagnetically catalyst was characterized by FT-IR spectroscopy, TGA, VSM, XRD, TEM and SEM