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Maryam Hajjami

Academic rank: Associate Professor
ORCID:
Education: PhD.
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Faculty: Basic Science
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Research

Title
Pd-4,6-Diamino-2-pyrimidinethiol Complex Supported on SBA-15 as a Useful and Retrievable Catalyst for Suzuki-Miyaura and Stille C-C Coupling Reactions
Type
JournalPaper
Keywords
4,6-Diamino-2-pyrimidinethiol · Stille coupling · Suzuki coupling
Year
2018
Journal catalysis letters
DOI
Researchers Kosar Nouri ، Maryam Hajjami ، Gouhar Azadi

Abstract

In this paper, Pd–4,6-diamino-2-pyrimidinethiol complex supported on SBA-15 as a novel heterogeneous catalyst with high activity for the reaction of aryl halides with phenylboronic acid or triphenyltin chloride have been well explored. The prepared catalyst has been characterized by Fourier transform infrared spectroscopy, X-ray diffraction spectroscopy, N 2 adsorption/ desorption isotherms (BET), transmission electron microscopy, scanning electron microscopy, thermogravimetric analysis and inductively coupled plasma analysis. The synthesized nanocatalyst could be easily recovered from the reaction mixture and reused five times without any loss in activity.