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Mohsen Nikoorazm

Academic rank: Professor
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Education: PhD.
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Faculty: Basic Science
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Research

Title
Palladium 2-mercapto-N-propylacetamide complex anchored onto MCM-41 as efficient and reusable nanocatalyst for Suzuki, Stille and Heck reactions and amination of aryl halides
Type
JournalPaper
Keywords
MCM-41; palladium; heterogeneous; C–C coupling reaction; amination
Year
2016
Journal APPLIED ORGANOMETALLIC CHEMISTRY
DOI
Researchers Mohsen Nikoorazm ، Arash Ghorbani-Choghamarani ، Nourolah Noori ، Bahman Tahmasbi

Abstract

A palladium 2-mercapto-N-propylacetamide complex supported on functionalized MCM-41 was prepared by a post-grafting method and considered as an efficient catalyst for C–C cross-coupling reactions between various aryl halides and sodium tetraphenylborate, phenylboronic acid, triphenyltin chloride or alkenes. Also, this catalyst shows good reactivity towards amination of aryl halides. This nanocatalyst was characterized using thermogravimetric analysis, X-ray diffraction, scanning electron microscopy, Fourier transform infrared spectroscopy, inductively coupled plasma and transmission electron microscopy techniques. Further results indicated that the heterogeneous catalyst could be recovered easily and reused several times without any loss of its catalytic activity.