2025 : 9 : 29

Mohsen Nikoorazm

Academic rank: Professor
ORCID:
Education: PhD.
ScopusId:
HIndex:
Faculty: Basic Science
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Research

Title
Fe3O4@MCM-41@Zn-Arg: as a novel, magnetically recoverable and ecofriendly nanocatalyst for the synthesis of disulfides, sulfoxides and 2,3-dihydroquinazolin-4(1H)-ones
Type
JournalPaper
Keywords
core-shell nanostructures; magnetic; sulfoxides; disulfides; 2,3- dihydroquinazolin-4(1H)-one
Year
2020
Journal INORGANIC AND NANO-METAL CHEMISTRY
DOI
Researchers Mohsen Nikoorazm ، Zahra Erfani

Abstract

The direct supporting of Zn-arginine complex on magnetic core-shell nanostructures (Fe3O4@MCM-41@Zn-Arg) was reported as a novel, heterogeneous and excellent nanocatalyst, which applied for the oxidation reaction of sulfides to sulfoxides, oxidative coupling of thiols to their corresponding disulfides and the synthesis of 2,3-dihydroquinazolin-4(1H)-one derivatives under mild conditions. The structure of the catalyst was studied by X-Ray diffraction, Fourier transform- infrared spectroscopy, thermogravimetric analysis, scanning electron microscopy, atomic absorption spectroscopy, and vibrating sample magnetometry techniques. The simple experimental procedure, very good catalytic activity, low cost, and excellent recycling are the noteworthy features of the currently employed heterogeneous catalytic system.