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Mohammad Soleiman-Beigi

Academic rank: Professor
ORCID:
Education: PhD.
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HIndex:
Faculty: Basic Science
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Research

Title
Synthesis of Symmetrical Triaryl Amines by Nano-CuO Catalyzed Buchwald-Hartwig Cross-coupling Reaction: NH2-Thiadiazole as a New N-source
Type
JournalPaper
Keywords
Symmetrical triarylamines, Selective N-arylation, Nitrogen-transfer reagent
Year
2018
Journal Organic Chemistry Research
DOI
Researchers Mohammad Soleiman-Beigi ، Fariba Mohammadi ، Mohammad Alikarami

Abstract

The one-pot synthesis of symmetrical triaryl amines using aryl halides and 5-methyl-1,3,4-thiadiazole-2-amine as a nitrogen-transfer reagent is reported. Copper nanoparticles improved rate and facility of the synthesis of triaryl amines without require the addition of any ligand. The introduction of a new N-source, using green solvents of PEG/H2O, normal atmospheric conditions and excellent yields under mild reaction conditions are other important features of this work. Keyw