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Mohammad Soleiman-Beigi

Academic rank: Professor
ORCID:
Education: PhD.
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HIndex:
Faculty: Basic Science
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Research

Title
A recyclable heterogeneous nanocatalyst of copper-grafted natural asphalt sulfonate (NAS@ Cu): characterization, synthesis and application in the Suzuki–Miyaura coupling reaction
Type
JournalPaper
Keywords
sodium natural asphalt sulfonate (Na-NAS)
Year
2020
Journal NEW JOURNAL OF CHEMISTRY
DOI
Researchers Homa Kohzadi ، Mohammad Soleiman-Beigi

Abstract

A new and efficient nanocatalyst was identified, synthesized and introduced and its catalytic activity was investigated in the Suzuki coupling reaction. This nanocatalyst can be synthesized by sulfonating natural asphalt as a high-carbon, cost-effective and accessible substrate using high-concentration sulfuric acid. After being neutralized by NaOH, it was transformed into sodium natural asphalt sulfonate (Na-NAS). Ultimately, the nanocatalyst was synthesized through a displacement reaction of sodium natural asphalt sulfonate with copper chloride. The solid derived (NAS@Cu) was identified using Transmission Electron Microscopy (TEM), Energy Dispersive Spectroscopy (EDS), Scanning Electron Microscopy (SEM), N2 sorption isotherms, Inductively Coupled Plasma (ICP), X-ray Diffraction (XRD), Thermogravimetric Analysis (TGA), Atomic Absorption Spectrometry (AAS) and Fourier-transform Infrared spectroscopy …