A simple and highly selective and sensitive catalytic adsorptive stripping voltammetric procedure for determination of ultra trace levels of chromium(VI) on hanging mercury drop electrode is reported. The method is based on the adsorptive preconcentration of the Cr(III)–dithiooxamide (rubeanic acid) complex and the utilization of the catalytic reaction in the presence of nitrate. At optimized conditions the calibration graph is linear from 0.01 to 6 ng/ml and detection limit is 0.002 ng/ml for accumulation time of 50 s. The interference of some common ions was studied and this method has been applied to the determination of chromium in food and waste water samples with satisfactory results.
