2025 : 9 : 29

shahriar abbasi

Academic rank: Professor
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Education: PhD.
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Faculty: Basic Science
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Research

Title
Ultrasound-assisted adsorption approach for desulfurization of n-heptane using nitrogen-doped magnetic carbon dot nanocomposite
Type
JournalPaper
Keywords
Adsorptive desulfurization N-doped magnetic carbon dot Nanocomposite Model fuel Thiophene compounds
Year
2023
Journal CHEMOSPHERE
DOI
Researchers Atousa Bahiraei ، shahriar abbasi ، Mohammad Tavakkoli Yaraki

Abstract

Desulfurization is an important process that not only affects the quality and performances of fuels but also is of great importance from environmental aspects. In this research, nitrogen-doped magnetic carbon dots nanocomposite was synthesized and characterized, and it’s potential in adsorptive removal of thiophenes (i.e., thiophene, benzothiophene, and dibenzothiophene) from n-heptane (i.e., as model fuel) was investigated. After optimization of adsorption process, the removal efficiency was obtained above 95% for all of studied thiophenes. Besides that, it was concluded that using ultrasound during the adsorption process could enhance the maximum adsorption capacity. Langmuir model was able to appropriately describe the adsorption isotherm data, where the maximum equilibrium adsorption capacities for thiophene, benzothiophene and dibenzothiophene were obtained as 90.22, 96.51 and 100.38 mgg− 1 , respectively. The analysis of kinetic data also revealed that all thiophenes were being adsorbed following Pseudo-second-order model. To regenerate the adsorbent, the desorption process was also investigated using different solvents under different conditions, methanol was found as effective solvent for regeneration. The proposed adsorbent was used successfully for the removal of pollutants in a gasoline sample.